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Beilstein J. Org. Chem. 2016, 12, 2757–2762, doi:10.3762/bjoc.12.272
Graphical Abstract
Scheme 1: Coordination of Cu(I) with the ambiphilic ligand 1 to form the catalyst 2.
Scheme 2: Proposed mechanism of direct arylation catalyzed by 2 (X = Cl/I; Ar = aryl).